Copper-catalyzed aminoalkynylation of alkenes with hypervalent iodine reagents† †Electronic supplementary information (ESI) available: Characterization data and experimental procedures. CCDC 1567005–1567007. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc03420b

Gold(i)-catalyzed [2 + 2 + 2] cycloaddition of allenamides, alkenes and aldehydes: a straightforward approach to tetrahydropyrans† †Electronic supplementary information (ESI) available: Characterization data and experimental procedures. CCDC 1038447–1038449. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00295h Click here for additional data file. Click here for additional data file.

Centro Singular de Investigación en Qúım (CIQUS) and Departamento de Qúımica Compostela, C/ Jenaro de la Fuente s/n, E-mail: [email protected]; fernan Instituto de Qúımica Orgánica General (CS Spain † Electronic supplementary information and experimental procedures. CCDC crystallographic data in CIF or o 10.1039/c5sc00295h ‡ HF and IV equally contributed to this w Cite this: Chem. Sci....

Oxalyl amide assisted palladium-catalyzed synthesis of pyrrolidones via carbonylation of γ-C(sp3)–H bonds of aliphatic amine substrates† †Electronic supplementary information (ESI) available: Experimental procedures, characterization data for all new compounds. CCDC 1048649. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc00519a

Copper-catalyzed silylation of p-quinone methides: new entry to dibenzylic silanes† †Electronic supplementary information (ESI) available: Experimental details, characterization and crystallographic data. CCDC 1414585. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5cc06653k Click here for additional data file. Click here for additional data file.

3. General procedure for synthesis of

Carbene catalyzed umpolung of α,β-enals: a reactivity study of diamino dienols vs. azolium enolates, and the characterization of advanced reaction intermediates† †Electronic supplementary information (ESI) available: Experimental procedures, compound characterization data, and X-ray crystallographic data of compounds 4b-Et and 4b-Me. CCDC 1014843 and 1014844. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc01027f Click here for additional data file. Click here for additional data file.

Metal-free di- and tri-fluoromethylation of alkenes realized by visible-light-induced perylene photoredox catalysis† †Electronic supplementary information (ESI) available: Experimental details, spectral data, and crystallographic results. CCDC 1533276 and 1533274. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c7sc01703k Click here for additional data file. Click here for additional data file.